From: sbharris@ix.netcom.com(Steven B. Harris) Newsgroups: rec.drugs.chemistry,sci.med,sci.chem,sci.med.nutrition Subject: Re: phosphoric acid Date: 14 Mar 1999 08:07:15 GMT In <36ef3f94.11687820@netnews.worldnet.att.net> Xiuh#tecuh#tli@world#net.att.net (Kolaga Xiuhtecuhtli) writes: >On Sun, 14 Mar 1999 00:55:01 GMT, zab10@bigfoot.com wrote: > >>This chemical is contained in soda like coke. >>What is its effects ? > >I think it's there for the bubbles... No, it's an acid put there to make the stuff taste tart (sour). Both carbonic acid and phosphoric acid taste much the same and are cheaper than citric and ascorbic acids, which are in so many kinds of fruit that we primates have developed a taste for acids, when combined with sweetness. Soft drinks are basically fake fruit juices for large-brained monkeys. The carbonation in your soft drink, the alcohol in your wine, and the mint in your toothpaste will all disgust your cat no end. But alcohol and acid, and flavors like mint and cola are all very common in fruits. Steve Harris, M.D. From: sbharris@ix.netcom.com(Steven B. Harris) Newsgroups: rec.drugs.chemistry,sci.med,sci.chem,sci.med.nutrition Subject: Re: phosphoric acid Date: 16 Mar 1999 03:48:18 GMT In <36ECA74C.6B931996@cs.uoregon.edu> Bret Wood <bretwood@cs.uoregon.edu> writes: >"Steven B. Harris" wrote: >> >> Xiuh#tecuh#tli@world#net.att.net (Kolaga Xiuhtecuhtli) writes: >> > >> >I think it's there for the bubbles... >> >> No, it's an acid put there to make the stuff taste tart (sour). Both >> carbonic acid and phosphoric acid taste much the same and are cheaper >> than citric and ascorbic acids. . . . . ><rest snipped> > >Actually, the carbonic acid IS for the bubbles. (Although the >question was just about phosphoric acid.) Actually, both. CO2 comes out of solution and goes up the back of your "nose" (oropharynx), giving you an acid sensation which is not duplicatable using any other gas soluble enough to give fizz like that. The acid properties of CO2 gas when it hits water are indispensible. >I was once told that carbonated drinks used to be made by dissolving >carbonic acid in the drink. But, since I don't think that you can >isolate solid H2CO3, I suspect that sodium carbonate, or sodium >bicarbonate and some acid were added, so that they would create >carbonic acid in the solution. They add CO2 under pressure. > (I've never seen solid H2CO3, >and a quick search of several on-line chemical supply companies >revealed that no-one sells solid H2CO3 either.) No, under normal pressures, 99% of it breaks down to CO2 and H2O at equalibrium. The CO2 stays in solution, however, so long as the partial pressure of the CO2 stays at about 1 atm. In your soft drink can there are about 100 molecules of CO2 floating around disolved in the water, for every molecule of H2CO3. >Now, they just bottle it under positive carbon dioxide pressure. >In essence it's the same thing, since CO2 and H2C03 are in >equilibrium in aqueous solution. > >CO2 + H2O <====> H2CO3 Yes, but again remember that most of the CO2 in the liquid is CO2, not H2CO3. >Perhaps the bubbles are popular because of the sensation, AND the >taste. Also, that would tend to answer a question which has been >in the back of my mind for quite a while.... Do carbonated drinks >really TASTE different after they go flat, or is it just that the >sensation of drinking them is different. Sour is a sensation. If you mean the mechanical fizz when pressure is removed, you could get that with any disolvable tasteless gas, such as Xenon or N2O. The tartness you could reproduce with another acid. I think you'd come close to soft drink taste, but there's still the matter of acid produced in the back of your throat and high in your nose where liquid doesn't go, that is hard reproduce with anything but CO2. Hmmm. Maybe a bit of SO2? > Since a flat carbonated >drink will have less carbonic acid, (since it has less carbon >dioxide, and the two chemicals are in equilibrium.) then I guess >it would affect the taste. > >-Bret "ex-chemist" Wood >-bretwood@cs.uoregon.edu From: sbharris@ix.netcom.com(Steven B. Harris) Newsgroups: sci.med,sci.chem,sci.med.nutrition Subject: Re: phosphoric acid Date: 16 Mar 1999 03:49:32 GMT In <36ECA87E.ED7A5F20@cs.uoregon.edu> Bret Wood <bretwood@cs.uoregon.edu> writes: >dnharring@aol.com wrote: > >> As to it's negative effects on teeth, bones, stomach lining, and Calcium >> absorption, I can't state with any certainty. I wouldn't drink it on >> an empty stomach, myself. > >Did you ever do the "nail in a glass of Coke" trick? > >Supposedly the cola will dissolve the nail overnight. (Overnight >seems a bit fast to me, but I've never actually done it myself.) > >As for phosphoric acid and stomach lining, our stomachs are full of >HCl anyway. Drinking Coke on an empty stomach can give you a nasty >case of heartburn, but I suspect it would take a lot of Coke to >seriously screw up your stomach's pH. (But then what do I know about >stomach chemistry.... :) > >BTW, does anyone know the approximate pH of the solution in a human >stomach? (empty, or just after a large meal?) > >-Bret Wood >-bretwood@cs.uoregon.edu It's about pH 1. Way below soft drinks. From: sbharris@ix.netcom.com(Steven B. Harris) Newsgroups: rec.drugs.chemistry,sci.med,sci.chem,sci.med.nutrition Subject: Re: phosphoric acid Date: 19 Mar 1999 10:44:09 GMT In <7cr9bk$27b4$1@uvaix7e1.comp.UVic.CA> mskala@csc.UVic.CA () writes: >CO2 is not exactly tasteless; it irritates the mucous membranes (possibly >by dissolving in them and creating acid? I'm not sure of that) and >produces a very distintive sensation. Yeah. Looking at what I wrote, it certainly gives the wrong impression. A breath of CO2 can be agony. >This is easy to observe if you drink pop out of a bottle that's nearly >empty and inhale some of the gas that collects above the liquid. This is >why CO2 is poisonous in large enough doses; a CO2/O2 atmosphere won't >support you even if it contains the right amount of O2. Yep. You're dead if you breathe more than about 10% CO2, in fact, and at risk above 7%. >As for Xe, I've heard it referred to as an anaesthetic, and that suggests >some biological activity, although that doesn't make much sense as it >doesn't react with anything. I could have heard wrong, or it could be >that it does something "mechanical" like dissolving in your blood and >unbalancing other solution equilibria. (?) Xenon is about as good an anaesthetic as nitrous oxide, which is to say-- not good enough for major surgery on its own, unless used hyperbarically-- but still suprisingly active. Like nitrous, it will give a pretty deep obtundation at 80% mix, in many people. The action of xenon is thought to be "mechanical" (if there is such a thing in the quantum world of atomic interactions, by disolving in the lipid bilayer of neurons, causing them to depolarize. Anaesthetics are active at about the same ratios they partition between water and oil. The oil apparently is like your neuronal membranes. Many anaesthetics probably don't work "chemically" (in the sense of forming a new covalent bond or binding to a specific receptor). >Anyway, it's not smart to go inhaling random gasses, and when we've been >doing something one way for a long time (such as CO2 in pop) it is >sometimes not a completely arbitrary choice. From: "Steve Harris" <sbharris@ix.RETICULATEDOBJECTcom.com> Newsgroups: sci.med.nutrition Subject: Re: Diet Soft drinks Date: Thu, 10 Apr 2003 01:30:17 -0700 Message-ID: <b739ur$f4v$1@slb0.atl.mindspring.net> ..com... > On Wed, 09 Apr 2003 23:56:39 -0400, Andrei Prokopiw > <Andrei.Prokopiw**NOSPAM**@Dartmouth.edu> wrote: > > > What are the main health concerns of soft drinks aside from sugar, i.e. > >Diet soft drinks. I hear the acid can cause problems with calcium > >absorption, but haven't read anything significant or official on this. COMMENT Rather, it's the free mineral acid (phosphoric) which has to be buffered in your urine to be excreted. Soda ends up effectively increasing your body's mineral acid load, and thus your calcium *excretion.* Both the phosphoric and the carbonic acid in pop chew on your tooth enamel, and the sugar provides bacteria in your mouth with substrate to produce lactic acid which does the same. Though to be fair, sugared cereals are far worse offenders as bacterial fodder than sugared drinks and juices (at least in non bottlefed adults). Finally, it's not completely clear that low cal soda pops with aspartame are safe when drunk in quantity on an empty stomach. The animal studies don't really address this, and aspartame's access to the brain as a neurotransmitter analog would be expected to be hugely influenced by the competition in amino acid pumps, ie, what else you're eating. So until we know the answers, I would recommend any sugar-free soda be drunk with meals, and if you must have pop between meals, make it the regular kind. Don't get me wrong. I don't that sodapop is the ultimate dietary evil of our modern food industry. That role is already taken by trans-fats/hydrogenated oils <g>. I'm just offended by how much money is spent on sodapop for *completely* empty fake fruit juice that rots your bones. Your monkey genes THINK you're drinking fruit juice, you see, even though the phytochemicals are missing. Just like your genes they think that the Crisco you're sucking down is really DHA containing marrow or brain from that large animal kill. It's all deception. From the TV we watch in place of real community relationships, to the cosmetics we apply to make your skin look younger, it's all lies. We live immersed in cheap and tawdry ways to fool our genes, and then fool our genes again when it comes time for payback. One of the few genuine things we do in a day is move our bowels, and due to the large number of fake foods most of us eat, even that doesn't work that well. Thus, the Aisle of Artificial Laxatives...* SBH * Out in the English Channel somewhere, so I hear. |